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王万辉
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王万辉副教授

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简介:

王万辉,副教授,博士生导师。2007年获日本政府奖学金资助,赴日本埼玉大学组攻读博士学位。2011年加入日本产业技术综合研究所(AIST)姬田雄一郎(Himeda Yuichiro)研究组开展博士后研究。2014年到大连理工大学精细化工国家重点实验室、石油与化学工程学院任职,同年入选大连理工大学首届“星海学者”人才培养计划(星海骨干层次)。目前,在国际知名期刊Chemical ReviewsNature ChemistryEnergy & Environmental ScienceACS Catalysis等发表SCI论文十余篇;参与撰写专著三章节;申请发明专利八项;主持国家自然科学青年基金1项、星海骨干人才基金1项、人才引进基金项目1项。

 

联系方式

办公电话:0427-2631809

办公传真:0427-2631809

电子邮箱地址:Chem_wangwh@dlut.edu.cn

研究室网页:http://molcatal.dlut.edu.cn/index.htm

 

主要学历

2014.02至今       大连理工大学,副教授、博士生导师、“星海骨干”

2011.05-2014.01     日本产业技术综合研究所 AIST),特别研究员

2008.04-2011.03     日本埼玉大学,工学博士

2004.09-2007.07     济南大学 硕士研究生

 

研究领域

新能源化学存储、CO2资源化利用、绿色催化

 

已发表的学术论文或著作

I.

1.       Wang, W.-H.*; Himeda, Y.*; Muckerman, J. T.*; Manbeck, G. F.; Fujita, E.* CO2 Hydrogenation to Formate and Methanol as an Alternative to Photo- and Electrochemical CO2 Reduction. Chemical Reviews, 2015, 115, 12936–12973.

2.       Wang, W.-H.; Ertem, M. Z.; Xu, S.; Onishi, N.; Manaka, Y.; Suna, Y.; Kambayashi, H.; Muckerman, J. T.;* Fujita, E.;* Himeda, Y.* Highly Robust Hydrogen Generation by Bioinspired Ir Complexes for Dehydrogenation of Formic Acid in Water: Experimental and Theoretical Mechanistic Investigations at Different pH. ACS Catalysis, 2015, 5, 5496–5504.

3.       Wang, W.-H.; Hull, J. F.; Muckerman, J. T.; Fujita, E.;* Himeda, Y.* Second-coordination-sphere and electronic effects enhance iridium(III)-catalyzed homogeneous hydrogenation of carbon dioxide in water near ambient temperature and pressure. Energy & Environmental Science 2012, 5, 7923-7926.

4.       Wang, W.-H.; Xu, S.; Manaka Y.; Suna, Y.; Kambayashi, H.; Muckerman, J. T.; Fujita, E.; Himeda, Y.* Highly efficient formic acid dehydrogenation using bio-inspired Ir complexes: A deuterium kinetic isotope effect study and mechanistic insight. ChemSusChem, 2014, 7, 1976-1983.

5.       Wang, W.-H.; Muckerman, J. T.;* Fujita, E.;* Himeda, Y.* Mechanistic insight through factors controlling effective hydrogenation of CO2 catalyzed by bio-inspired proton responsive iridium(III) complexes. ACS Catalysis, 2013, 3, 856-860.

6.       Wang, W.-H.; Hull, J. F.; Muckerman, J. T.; Fujita, E.; Himeda, Y.* Highly Efficient D2 Generation by Dehydrogenation of Formic Acid in D2O through H+/D+ Exchange on Iridium Catalyst: Application to the Synthesis of Deuterated Compounds by Transfer Deuterogenation. Chemistry – A European Journal 2012, 18, 9397-9404.

7.       Wang, W.-H.; Suna, Y.; Himeda, Y.;* Muckerman, J. T.; Fujita, E. Functionalized cyclopentadienyl rhodium(III) bipyridine complexes: Synthesis, characterization, and catalytic application in hydrogenation of ketones. Dalton Transactions, 2013, 42, 9628-9636.

8.       Wang, W.-H.; Muckerman, J. T.; Fujita, E.; Himeda, Y.* Hydroxyl-substituted pyridine-like N-heterocycles: Versatile ligands in organometallic catalysis. New Journal of Chemistry, 2013, 37, 1860-1866.

9.       Wang, W.-H.; Himeda, Y.; Muckerman, J. T.; Fujita, E.* Interconversion of CO2 and formic acid using bio-inspired catalysts under mild conditions in water. Advances in Inorganic Chemistry, 2014, 66, 189-222.

10.   Manaka Y.; Wang, W.-H.;* Suna, Y.; Kambayashi H.; Muckerman, J. T.; Fujita, E.; Himeda, Y.* Efficient H2 generation from formic acid using an azole complex in water. Catalysis Science & Technology, 2014, 4, 34-37.

11.   Badiei, Y. M. Wang, W.-H. Hull, J. F.; Szalda, D. J.; Muckerman, J. T.;* Himeda, Y.;* Fujita, E.* Cp*Co(III) catalysts with proton-responsive ligands for carbon dioxide hydrogenation in aqueous media. Inorganic Chemistry, 2013, 52, 12576-12586. [§并列第一]

12.   Wang, W.-H.; Wang, X.-B.; Kodama, K.; Hirose, T.*; Zhang, G.-Y. Novel chiral ammonium ionic liquids as efficient organocatalysts for asymmetric Michael addition of aldehydes to nitroolefins. Tetrahedron 2010, 66, 4970-4976.

13.   Wang, W.-H.; Abe, T.; Wang, X.-B.; Kodama, K.; Hirose, T.*; Zhang, G.-Y. Self-assembled proline-amino thioureas as efficient organocatalysts for asymmetric Michael addition of aldehydes to nitroolefins. Tetrahedron: Asymmetry 2010, 21, 2925-2933.

14.   Hull, J. F.;* Himeda, Y.;* Wang, W.-H.; Hashiguchi, B.; Periana, R.; Szalda, D. J.; Muckerman, J. T.; Fujita, E.* Reversible hydrogen storage using CO2 and a proton-switchable iridium catalyst in aqueous media under mild temperatures and pressures. Nature Chemistry 2012, 5, 383-388.

15.   Lewandowska-Andralojc, A.; Polyansky, D. E.; Wang, C.-H.; Wang, W.-H.; Himeda, Y.; Fujita, E.* Efficient water oxidation with organometallic iridium complexes as precatalysts. Physical Chemistry Chemical Physics 2014, 16, 11976-11987.

16.   Suna, Y.; Ertem, M. Z.; Wang, W.-H.; Kambayashi, H.; Manaka, Y.; Muckerman, J. T.; Fujita, E.; Himeda, Y.;* Positional Effects of Hydroxy Groups on Catalytic Activity of Proton-Responsive Half-Sandwich Cp*Iridium(III) Complexes. Organometallics 2014, 33, 6519-6530.

17.   Onishi, N.; Xu, S.; Manaka, Y.; Suna, Y.; Wang, W.-H.; Muckerman, J. T.; Fujita, E.; Himeda, Y.* CO2 Hydrogenation Catalyzed by Iridium Complexes with a Proton-Responsive Ligand. Inorg. Chem. 2015, 54, 5114–5123.

18.   Xu, S.; Onishi, N.; Tsurusaki, A.; Manaka, Y.; Wang, W.-H.; Muckerman, J. T.; Fujita, E.; Himeda, Y. Efficient Cp*Ir Catalysts with Imidazoline Ligands for CO2 Hydrogenation. European Journal of Inorganic Chemistry 2015, 5591-5594.

II.书

1.       Wang, W.-H.; Himeda, Y. Recent advances of homogeneous iridium catalysts in aqueous solution. In Iridium: Occurrence, Characteristics and Applications, Fukui, C.; Ono, M. Eds., Nova Science Publishers: New York, 2012, pp39-68.

2.       Wang, W.-H.; Himeda, Y. Recent advances in transition metal-catalysed homogeneous hydrogenation of carbon dioxide in aqueous media. In Hydrogenation, Karamé, I. Ed., InTech Publisher, 2012, pp249-268.

3.      Himeda, Y; Wang, W.-H. Application of carbon dioxide in hydrogen storage: homogeneous hydrogenation of carbon dioxide and dehydrogenation of formic acid. In New and future developments in catalysis: activation of carbon dioxide, Suib, S.L. Ed., Elsevier, 2013, pp171-188.

III.申

1.       Himeda, Y.; Wang, W.-H. Catalyst for dehydrogenation of formic acid and their application in generation of H2, D2, and HD. 日本专利申请号2012-15087, 国际专利申请号PCT/JP2013/5160.

2.       Himeda, Y.; Wang, W.-H. Catalyst for CO2 hydrogenation and HCO2H dehydrogenation and their application in H2 storage and release. 日本专利申请号2012-62042.

3.       Himeda, Y.; Wang, W.-H.; Manaka Y.; Suna, Y. Hydrogen generation method by catalytic dehydrogenation of formic acid. 日本专利申请号2013-213576.

4.       Himeda, Y.; Wang, W.-H.; Suna, Y.; Manaka Y. Hydrogen generation method by catalytic dehydrogenation of formic acid. 日本专利申请号:2013-238936.

5.       王万辉、陆文多、包明, 一种用质子响应型铱配合物催化氨硼烷水解制氢的方法. 专利申请号:201510246683.3.

6.       王万辉、葛凯、包明, 一种由ab-不饱和醛酮制备烯丙醇类化合物的方法. 专利申请号:201510246826.0.

7.       王万辉、杨堃、包明, 一种用催化氨硼烷水解制氢的铱催化剂、制备方法及其应用. 专利申请号:201510245714.3.

8.       王万辉、唐会鹏、包明, 一种用含硫铱配合物催化CO2加氢还原的方法. 专利申请号:201510980763.1

 


 

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School of petroleum and chemical engineering, Dalian university of technology